HCID 178418287, 화합물 → HCID 178461263, 화합물

HRID 1852698노트

반응식

HRID 1852698 반응식
[CH3:1][C@H:2]1[CH2:7][CH2:6][C@H:5]([CH2:8][OH:9])[CH2:4][CH2:3]1.[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1>C(Cl)Cl>[CH3:1][C@H:2]1[CH2:7][CH2:6][C@H:5]([CH:8]=[O:9])[CH2:4][CH2:3]1

참가 물질

4

반응물 2

HCID 178418287HCID 178418287, 화합물HCID 178461264HCID 178461264, 화합물

생성물 1

HCID 178461263HCID 178461263, 화합물

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

To a solution of trans-(4-methylcyclohexyl)methanol (160 g, 1.25 mol) in DCM (1500 mL) was added pyridinium chlorochromate (405 g, 1.88 mol) at 0° C., and the mixture was stirred at room temperature for 2 h. It was filtered and the filtrate was concentrated in vacuo to give trans-4-methylcyclohexanecarbaldehyde.

후처리

  1. filtrationIt was filtered
  2. concentrationthe filtrate was concentrated in vacuo

출처 및 근거

ORD 기록
ord-8e224047d38d439bbe7f64321a7fbae5
출처 데이터셋
uspto-grants-2015_02
특허 번호
US08962611B2

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