909135-23-5 → HCID 59193687, 화합물
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I[C:2]1[C:7]([CH3:8])=[C:6]([CH3:9])[CH:5]=[CH:4][C:3]=1[N+:10]([O-:12])=[O:11]>CN(C=O)C.[Cu]>[CH3:8][C:7]1[C:6]([CH3:9])=[CH:5][CH:4]=[C:3]([N+:10]([O-:12])=[O:11])[C:2]=1[C:2]1[C:3]([N+:10]([O-:12])=[O:11])=[CH:4][CH:5]=[C:6]([CH3:9])[C:7]=1[CH3:8]참가 물질
4
실험 절차
In 20 ml of a DMF solvent, 5.5 g (20 mmol) of 2-iodo-3,4-dimethyl-1-nitrobenzene and 10 g (155 mmol) of copper powder were heated at 150° C. for 48 hours. After the completion of the reaction, copper powder was removed by filtration and thereafter, the resultant was extracted using ethyl acetate, dried/concentrated, and then purified by column chromatography (ethyl acetate:hexane=1:10) to obtain 2.9 g (0.96 mmol) of 2,3,2′,3′-tetramethyl-6,6′-dinitrobiphenyl (34) (yield was 96%).
후처리
- customwas removed by filtration
- extractionthe resultant was extracted
- concentrationdried/concentrated
- custompurified by column chromatography (ethyl acetate:hexane=1:10)
출처 및 근거
- ORD 기록
- ord-e1c8ee4e11a448788f5cd1f305946643
- 출처 데이터셋
- uspto-grants-2015_02
- 특허 번호
- US08962898B2
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