HCID 59193687, 화합물 → HCID 59193680, 화합물
반응식
[CH3:1][C:2]1[C:7]([CH3:8])=[CH:6][CH:5]=[C:4]([N+:9]([O-])=O)[C:3]=1[C:12]1[C:17]([N+:18]([O-])=O)=[CH:16][CH:15]=[C:14]([CH3:21])[C:13]=1[CH3:22]>CO.[Pd]>[CH3:8][C:7]1[C:2]([CH3:1])=[C:3]([C:12]2[C:17]([NH2:18])=[CH:16][CH:15]=[C:14]([CH3:21])[C:13]=2[CH3:22])[C:4]([NH2:9])=[CH:5][CH:6]=1참가 물질
4
실험 절차
3.0 g (10 mmol) of the compound (34) and 500 mg (5 mol %) of 10% Pd/C were added to 50 ml of a methanol solvent and were stirred for 12 hours under hydrogen atmosphere. After the completion of the reaction, solid matter was removed by filtration and thereafter, the resultant was purified by column chromatography (ethyl acetate:hexane=1:5) to obtain 2.4 g (10 mmol) of 5,6,5′,6′-tetramethylbiphenyl-2,2′-diamine (35) (yield was 100%).
후처리
- customAfter the completion of the reaction, solid matter
- customwas removed by filtration
- customthe resultant was purified by column chromatography (ethyl acetate:hexane=1:5)
출처 및 근거
- ORD 기록
- ord-5b92f26b361f4cdd90712213f60dc8cf
- 출처 데이터셋
- uspto-grants-2015_02
- 특허 번호
- US08962898B2
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