Water → N-acetyl-2-benzylsulfinylacetamide

HRID 1855757노트

반응식

HRID 1855757 반응식
[C:1]([NH:4][C:5](=[O:15])[CH2:6][S:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)(=[O:3])[CH3:2].[OH2:16]>>[C:1]([NH:4][C:5](=[O:15])[CH2:6][S:7]([CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)=[O:16])(=[O:3])[CH3:2]

참가 물질

3

반응물 2

HCID 962WaterHCID 12837900HCID 12837900, 화합물

생성물 1

HCID 20540297N-acetyl-2-benzylsulfinylacetamide

실험 절차

To a solution of 0.011 mole of NaIO4 in 25 ml. of water which has been cooled to 5° C. is added 0.01 mole of N-acetyl-2-(benzylthio) acetamide. The reaction mixture is allowed to warm to room temperature and then stirred overnight and concentrated to dryness. Chromatography of the residue on 200 g. of silica gel eluting with ethyl acetate in hexane (25-75%) gives N-acetyl-2-benzylsulfinylacetamide.

후처리

  1. concentrationconcentrated to dryness

출처 및 근거

ORD 기록
ord-0b6c84c0f8b944da87f945eab402b1b5
출처 데이터셋
uspto-grants-1980_08
특허 번호
US04216160

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