Oct-2-ene → Methyl-undec-9-enoate

HRID 1855975

반응식

HRID 1855975 반응식
[C:1]([O:20][CH3:21])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11]CCCCCCC.CC=CCCCCC>>[C:1]([O:20][CH3:21])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH:10][CH3:11]

참가 물질

3

반응물 2

HCID 8126Oct-2-eneHCID 5364509Methyl Oleate

생성물 1

HCID 62588Methyl-undec-9-enoate수율 5%

실험 절차

Reaction was carried out in the same manner as in Example 1, except that a mixture of 1 ml of methyl oleate and 1 ml of 2-octene was used in place of 1 ml of the methyl oleate, the reaction temperature was 70° C., and the reaction time was 17 hours. There were obtained methyl 9-undecenoate in a yield of about 5% and methyl 9-pentadecanoate in a yield of about 7% (estimated from the chromatogram). Besides, metathesis products were obtained independently from methyl oleate and 2-octene.

후처리

  1. customReaction
  2. customwas 70° C.

출처 및 근거

ORD 기록
ord-2dd0dc184fc1498498593a91c8adadba
출처 데이터셋
uspto-grants-1980_08
특허 번호
US04217299

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