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Methyl (3E)-4-phenyl-3-butenoate → (3E)-4-Phenyl-3-buten-1-ol

HRID 1858778
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반응식

HRID 1858778 반응식
[C:1]1(/[CH:7]=[CH:8]/[CH2:9][C:10](OC)=[O:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[C:1]1(/[CH:7]=[CH:8]/[CH2:9][CH2:10][OH:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1
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참가 물질

4

반응물 2

HCID 5370649Methyl (3E)-4-phenyl-3-butenoateHCID 21226445Aluminium lithium hydride

생성물 1

HCID 5370624(3E)-4-Phenyl-3-buten-1-ol

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

In an analogous manner to that described in Example 5(b), by reducing methyl (E)-4-phenyl-but-3-enoate by means of lithium aluminium hydride in tetrahydrofuran there was obtained (E)-4-phenyl-but-3-en-1-ol, which was converted into (E)-4-phenyl-but-3-enyl methanesulphonate in analogy to the procedure described in J.Chem.Soc. Perk.Trans. 1 (1988), (6),1517-1519 for the preparation of the (Z) isomer.

출처 및 근거

ORD 기록
ord-a73656bca2814fc78135a7bce93f591e
출처 데이터셋
uspto-grants-2000_11
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06150526

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