Quinoline → (Z)-dodec-2-en-1-ol

HRID 1858886

반응식

HRID 1858886 반응식
C(O)/C=C\CCCCCCC.[CH2:12]([OH:24])[C:13]#[C:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23].N1C2C(=CC=CC=2)C=CC=1>>[CH2:12]([OH:24])/[CH:13]=[CH:14]\[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23]

참가 물질

4

반응물 3

HCID 7047QuinolineHCID 1712322Dodec-2-yn-1-olHCID 53649532-Decen-1-ol, (Z)-

생성물 1

HCID 5364955(Z)-dodec-2-en-1-ol

실험 절차

cis-2-Dodecen-1-ol was prepared as described above for cis-2-decen-1-ol except that 35 g of 2-dodecyn-1-ol, 1.0 g of catalyst, and 3.0 ml of quinoline was used. A clear oil, 33.86 g, was obtained after kugelrohr distillation. 1H NMR δ 5.57 (m, 2), 4.19 (d, 2, J=5 Hz), 2.07 (dd, 2, J=6, 12 Hz), 1.5-1.2 (m, 14), 0.88 (t, 3, J=7 Hz).

후처리

  1. customA clear oil, 33.86 g, was obtained
  2. distillationafter kugelrohr distillation

출처 및 근거

ORD 기록
ord-447466dc21d6434cb6bbe3669fa8f633
출처 데이터셋
uspto-grants-2000_11
특허 번호
US06153589

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