Tetrahydrofuran → HCID 178426004, 화합물

HRID 1862196노트

반응식

HRID 1862196 반응식
[CH2:1]([Li])[CH2:2][CH2:3][CH3:4].[Cl-:6].[Cl-].[Cl-].C[Zr:10](C)(C)(C)(C)[CH:11]1[CH:15]=[CH:14][CH:13]=[CH:12]1.O1CCC[CH2:21]1>>[Cl-:6].[Cl-:6].[CH3:1][C:2]1[C:11]([Zr+2:10])([CH3:12])[C:15]([CH3:21])=[C:14]([CH3:13])[C:3]=1[CH3:4]

참가 물질

4

반응물 3

HCID 8028Tetrahydrofuran2회HCID 178418339ButyllithiumHCID 178477801HCID 178477801, 화합물

생성물 1

HCID 178426004HCID 178426004, 화합물

실험 절차

A solution of 1.39 g of 1′H, 1′H, 2′H, 2′H-perfluorooctylcyclopentadiene from Example 5 in 50 ml of tetrahydrofuran is admixed at −78° C. with 2.1 ml of 1.65 M butyllithium solution and then admixed with a cooled suspension of 1.11 g of pentamethylcyclopentadienylzirconium trichloride in 30 ml of tetrahydrofuran. The mixture is allowed to warm to room temperature and the solvent is removed under reduced pressure. The product is isolated by means of extraction with methylene chloride and pentane.

후처리

  1. customthe solvent is removed under reduced pressure
  2. customThe product is isolated by means of extraction with methylene chloride and pentane

출처 및 근거

ORD 기록
ord-47fa57dbd40946f58b382c9de54c01fc
출처 데이터셋
uspto-grants-2003_03
특허 번호
US06537943B1

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