3-Bromo-2-methyl-1-propene → 5,7-Dimethoxy-3-methyl-1-naphthol

HRID 1870071

반응식

HRID 1870071 반응식
C(N(CC)[C:4](=[O:15])[C:5]1[CH:10]=[C:9]([O:11][CH3:12])[CH:8]=[C:7]([O:13][CH3:14])[CH:6]=1)C.Br[CH2:19][C:20]([CH3:22])=[CH2:21].CC(CSC[C@H]1O[C@@H](N2C3NC=NC(=O)C=3N=C2)[C@H](O)[C@@H]1O)C>>[CH3:12][O:11][C:9]1[CH:8]=[C:7]([O:13][CH3:14])[CH:6]=[C:5]2[C:10]=1[CH:19]=[C:20]([CH3:22])[CH:21]=[C:4]2[OH:15]

참가 물질

4

반응물 3

HCID 3577853-Bromo-2-methyl-1-propeneHCID 4075317N,N-diethyl-3,5-dimethoxybenzamideHCID 178454970HCID 178454970, 화합물

생성물 1

HCID 154041135,7-Dimethoxy-3-methyl-1-naphthol수율 50%

실험 절차

5,7-Dimethoxy-3-methyl-1-naphthol is synthesized from N,N-diethyl-3,5-dimethoxybenzamide and 3-bromo-2-methylpropene according to the method described by Sibi et al. (J. Org. Chem. 1986, Vol. 51, pp. 271-273). The yield is approximately 50%.

출처 및 근거

ORD 기록
ord-ef76600b6f3440a9a463417d54c86752
출처 데이터셋
uspto-grants-2000_08
특허 번호
US06096246

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