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Diethyl Ether → HCID 68439530, 화합물

HRID 1877333
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HRID 1877333 반응식
[C:1]1([C@H:7]([CH2:11]C(O)=O)[C:8]([OH:10])=O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:15][Li].C([O:19][CH2:20][CH3:21])C>>[C:1]1([C@H:7]([CH2:11][C:20](=[O:19])[CH3:21])[C:8](=[O:10])[CH3:15])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

4

반응물 3

HCID 3283Diethyl EtherHCID 736146(+)-Phenylsuccinic acidHCID 178418348HCID 178418348, 화합물

생성물 1

HCID 68439530HCID 68439530, 화합물

실험 절차

(S)-3-Phenylhexane-2,5-dione was synthesized from (S)-2-phenylsuccinic acid with methyllithium in diethyl ether. The analytical data apart from the optical rotation and CD corresponds to the product formed by means of PigD catalysis (FIGS. 10 and 16).

후처리

  1. customThe analytical data apart from the optical rotation and CD corresponds to the product formed by means of PigD catalysis (FIGS. 10 and 16)

출처 및 근거

ORD 기록
ord-df9c327b807241d2a597305e2eeddc6b
출처 데이터셋
uspto-grants-2012_11
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08309742B2

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