Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → 2-Oxopropanal propylhydrazone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Methylglyoxal | HCID 880 | — |
| 반응물 | Hydrazine, propyl-, ethanedioate (1:1) | HCID 96079 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-Oxopropanal propylhydrazone | HCID 86650488 | 119.6% |
반응 단계
Acetic acid (2.9 mL, 50 mmol) was added to a solution of n-propylhydrazine oxalate (5.0 g, 30 mmol) in water (100 mL). This mixture was added to a solution of pyruvaldehyde (4.39 g, 3.96 mL, 24.4 mmol) in water (500 mL). The solution was stirred at room temperature overnight. The aqueous phase was extracted with CH2Cl2 (4×) and the combined organic extracts were washed with saturated aqueous NaHCO3, dried over Na2SO4, filtered and concentrated to afford 2-oxopropanal propylhydrazone (3.74 g, 96%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08318762B2 |
| 출처 데이터셋 | uspto-grants-2012_11 |
| ORD ID | ord-7796eb213dd844c38e6977f5798fc803 |
| 출처 메모 | uspto-grants-2012_11 |