참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Mesitylene | HCID 7947 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 반응물 | Tert-Butyl nitrite | HCID 10906 | — |
| 반응물 | Benzaldehyde, 3,5-dimethyl- | HCID 34225 | — |
| 반응물 | 3,5-Dimethylbenzonitrile | HCID 89718 | — |
| 반응물 | N-[(3,5-Dimethylphenyl)methylidene]hydroxylamine | HCID 71401900 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | Benzenemethanol, 3,5-dimethyl-, 1-acetate | HCID 12229212 | — |
반응 단계
Mesitylene (1 ml), t-butyl nitrite (1 mmol), N-hydroxyphthalimide (0.2 mmol), and acetic acid (1 ml) were placed in a flask and were stirred at 60° C. in an atmosphere of argon gas (1 atm=0.101 MPa) for 20 hours. The resulting reaction mixture was analyzed to find that 3,5-dimethylbenzaldehyde oxime, 3,5-dimethylbenzaldehyde, 3,5-dimethylbenzonitrile, and 3,5-dimethylphenylmethyl acetate were formed in yields of 61%, 3%, 4%, and less than 1%, respectively.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06768023B2 |
|---|
| 출처 데이터셋 | uspto-grants-2004_07 |
|---|
| ORD ID | ord-6dbe78615a4b4b198597b09087a4073c |
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| 출처 메모 | uspto-grants-2004_07 |
|---|
