2'-Aminoacetophenone → HCID 178450482, 화합물

HRID 1885171

반응식

HRID 1885171 반응식
[C:1]([C:6](=[CH:12]OCC)[C:7]([O:9][CH2:10][CH3:11])=[O:8])(=[O:5])[CH2:2][CH2:3][CH3:4].[NH2:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[C:23](=[O:25])[CH3:24]>>[C:1]([C:6](=[CH:12][NH:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[C:23](=[O:25])[CH3:24])[C:7]([O:9][CH2:10][CH3:11])=[O:8])(=[O:5])[CH2:2][CH2:3][CH3:4]

참가 물질

3

반응물 2

HCID 110862'-AminoacetophenoneHCID 3359484Ethyl 2-butyryl-3-ethoxyacrylate

생성물 1

HCID 178450482HCID 178450482, 화합물

실험 절차

A mixture of ethyl 2-butyryl-3-ethoxyacrylate (23.5 g, 0.11 mol) and 2'-aminoacetophenone (13.5 g, 0.1 mol) was warmed on a steam bath for 10 minutes. Crystallisation from petroleum ether gave ethyl 2-butyryl-3-(2-acetylphenylamino)acrylate as a mixture of E/Z isomers (14.9 g, 49%).

후처리

  1. temperaturewas warmed on a steam bath for 10 minutes
  2. customCrystallisation from petroleum ether

출처 및 근거

ORD 기록
ord-18a5463c6df942f88a2780cefe61fa27
출처 데이터셋
uspto-grants-1992_09
특허 번호
US05143920

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