Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → P-Toluic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | P-Xylene | HCID 7809 | — |
| 반응물 | 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl acetate | HCID 265566 | — |
| 촉매 | Cobalt diacetate | HCID 6277 | — |
| 촉매 | Manganous Acetate | HCID 12525 | — |
| 생성물 | P-Toluic Acid | HCID 7470 | — |
| 생성물 | Terephthalic Acid | HCID 7489 | — |
| 생성물 | 4-Formylbenzoic acid | HCID 12088 | — |
반응 단계
A mixture of 2 mmol of p-xylene, 0.1 mmol of N-acetoxyphthalimide, 0.01 mmol of cobalt(II) acetate, 0.01 mmol of manganese(II) acetate and 2 ml of acetic acid was stirred at 100° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 14 hours and thereby yielded terephthalic acid, p-toluic acid and p-carboxybenzaldehyde in yields of 79%, 8% and 5%, respectively.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07741514B2 |
| 출처 데이터셋 | uspto-grants-2010_06 |
| ORD ID | ord-ae68f3c87b994f6b992ba57440c5f57a |
| 출처 메모 | uspto-grants-2010_06 |