Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → Benzoic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Cumene | HCID 7406 | — |
| 반응물 | 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl acetate | HCID 265566 | — |
| 촉매 | Cobalt(II) acetate tetrahydrate | HCID 61372 | — |
| 촉매 | Manganese acetate tetrahydrate | HCID 93021 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | Benzoic Acid | HCID 243 | — |
| 생성물 | Acetophenone | HCID 7410 | — |
| 생성물 | 2-Phenyl-2-propanol | HCID 12053 | — |
반응 단계
A mixture of 1.202 g (10 mmol) of isopropylbenzene, 0.205 g (1 mmol) of N-acetoxyphthalimide, 0.025 g (0.1 mmol) of cobalt(II) acetate tetrahydrate, 0.025 g (0.1 mmol) of manganese(II) acetate tetrahydrate and 15 ml of acetic acid was stirred at 100° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 8 hours and thereby yielded benzoic acid, acetophenone and 2-phenyl-2-propanol in yields of 30%, 9% and 2% (analyzed by gas chromatography), respectively, with a conversion from isopropylbenzene of 65%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07741514B2 |
| 출처 데이터셋 | uspto-grants-2010_06 |
| ORD ID | ord-c007daef6b9a4bf3b9fca14c572b554e |
| 출처 메모 | uspto-grants-2010_06 |