Gallium, chlorodimethyl- → Diethylaminopropyl(dimethyl)gallium

HRID 1886209노트

반응식

HRID 1886209 반응식
[CH2:1]([N:3]([CH2:6][CH2:7][CH2:8][Li])[CH2:4][CH3:5])[CH3:2].[Cl-].[CH3:11][Ga+:12][CH3:13]>CCCCC>[CH2:1]([N:3]([CH2:6][CH2:7][CH2:8][Ga:12]([CH3:13])[CH3:11])[CH2:4][CH3:5])[CH3:2]

참가 물질

4

반응물 2

HCID 81329Gallium, chlorodimethyl-HCID 178506873HCID 178506873, 화합물

생성물 1

HCID 14531883Diethylaminopropyl(dimethyl)gallium

시약·촉매·용매 1

HCID 8003Pentane용매2회

실험 절차

3.6 g (30 mmol) of diethylaminopropyllithium dissolved in 100 ml of pentane are added to a solution of 4 g (30 mmol) of dimethylgallium chloride in 50 ml of pentane at -78°. The solution is allowed to come to room temperature and is stirred for a further 24 hours. The working up is carried out analogously to Example 1. Instead of the distillation, a sublimination is carried out. Diethylaminopropyl(dimethyl)gallium with an M.p. of 43°-45° is obtained.

후처리

  1. customto come to room temperature
  2. distillationInstead of the distillation

출처 및 근거

ORD 기록
ord-d1032530d17544e882110d2f91e7c718
출처 데이터셋
uspto-grants-1992_09
특허 번호
US05149853

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