Gallium, chlorodimethyl- → (3-Dimethylarsinopropyl)-dimethylgallium

HRID 1886210노트

반응식

HRID 1886210 반응식
[CH3:1][As:2]([CH3:7])[CH2:3][CH2:4][CH2:5]Cl.[Mg].[Cl-].[CH3:10][Ga+:11][CH3:12]>C(OCC)C>[CH3:1][As:2]([CH3:7])[CH2:3][CH2:4][CH2:5][Ga:11]([CH3:12])[CH3:10]

참가 물질

5

반응물 3

HCID 81329Gallium, chlorodimethyl-HCID 5462224MagnesiumHCID 85772197(3-Dimethylarsinopropyl)chloride

생성물 1

HCID 86745768(3-Dimethylarsinopropyl)-dimethylgallium

시약·촉매·용매 1

HCID 3283Diethyl Ether용매2회

실험 절차

5.47 g (30 mmol) of (3-dimethylarsinopropyl)chloride are added to 1.44 g (60 mmol) of magnesium chips in 100 ml of diethylether at 20° C., and then the mixture is heated under reflux for two hours. The solution is allowed to come to room temperature, 4.0 g (30 mmol) of dimethylgallium chloride is 50 ml of diethylether are added, and the solution is refluxed again for two hours. The working up is carried out analogously to Example 1. (3-Dimethylarsinopropyl)-dimethylgallium is obtained as a clear liquid with a B.p. of 86° C./0.01 mbar.

후처리

  1. temperaturethe mixture is heated
  2. temperatureunder reflux for two hours
  3. customto come to room temperature
  4. additionare added
  5. temperaturethe solution is refluxed again for two hours

출처 및 근거

ORD 기록
ord-534f2af40de14452a7b4c3316242336a
출처 데이터셋
uspto-grants-1992_09
특허 번호
US05149853

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