참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Octadecyl isocyanate | HCID 66988 | — |
| 반응물 | 1,1,2,2-Tetrahydroperfluorodecanethiol | HCID 542755 | — |
| 반응물 | Diazabicyclooctane | HCID 66583054 | — |
| 생성물 | C18H37Nhcosch2CH2C8F17 | HCID 131719351 | — |
반응 단계
Octadecyl isocyanate (29.5 g, 0.1 mole), C8F17CH2CH2SH (48 g, 0.1 moles) and 2.2.2 diazabicyclooctane (0.1 g) were mixed under nitrogen and heated to 100° C. with stirring for 6 hours. An infrared spectrum showed no --NCO absorption, indicating completion of the reaction. The product is a white wax, melting at 85°-89° C. NMR showed proton resonances at 4.7 ppm (1 proton NH), 3.2 ppm (2 protons CH2CH2NH), 3.1 ppm (2 protons CH2SCO), 2.5 ppm (2 protons C8F17CH2), 1.3 ppm (32 protons CH3 (CH2)16) and 0.8 ppm (3 protons CH3 (CH2)16).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05571779 |
|---|
| 출처 데이터셋 | uspto-grants-1996_11 |
|---|
| ORD ID | ord-d4b4f189ef9f411abd0a3024c3dfa362 |
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| 출처 메모 | uspto-grants-1996_11 |
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