Aluminium lithium hydride → HCID 21474772, 화합물
반응식
[C:1]1([CH2:7][CH2:8][O:9][CH2:10][CH:11]([OH:16])[CH2:12][N:13]=[N+]=[N-])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[C:1]1([CH2:7][CH2:8][O:9][CH2:10][CH:11]([OH:16])[CH2:12][NH2:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1참가 물질
4
실험 절차
A procedure similar to that described in Preparation 13 was repeated, except that 5.30 g of 3-(2-phenylethoxy)-2-hydroxypropylazide (prepared as described in Preparation 56), 1.85 g of lithium aluminum hydride and 120 ml of anhydrous tetrahydrofuran were used, to give 4.47 g of the title compound as a colorless oil having an Rf value of 0.09 (on silica gel thin layer chromatography, using a 10:1 by volume mixture of ethyl acetate and methanol as the developing solvent).
후처리
- customA procedure similar to that described in Preparation 13
출처 및 근거
- ORD 기록
- ord-e73711e75ed346ad82f06cf59385e9d4
- 출처 데이터셋
- uspto-grants-1996_11
- 특허 번호
- US05578620
반응 노트
불러오는 중…