HCID 13273321, 화합물 → HCID 13273322, 화합물

반응식

[F:1][CH:2]([F:22])[C:3]([C:15]([O:17]C(C)(C)C)=[O:16])([CH2:11][CH2:12][CH:13]=[CH2:14])[C:4]([O:6]C(C)(C)C)=[O:5]>FC(F)(F)C(O)=O>[C:15]([C:3]([CH:2]([F:1])[F:22])([CH2:11][CH2:12][CH:13]=[CH2:14])[C:4]([OH:6])=[O:5])([OH:17])=[O:16]

참가 물질

실험 절차

2-Difluoromethyl 2(tert-butoxycarbonyl)-5-hexenoic acid, tert-butyl ester prepared as in Step B (5 mM, 1.600 g) is dissolved in trifluoroacetic acid (10 ml) at 0° C. After stirring for 1.5 hours at room temperature, the solvent is evaporated in vacuo yielding a white solid. 1.040 g (quantitative yield). Mp: 80°-81° C.

후처리

customthe solvent is evaporated in vacuo
customyielding a white solid

출처 및 근거

ORD 기록: ord-1e2125984a1e4bfcbf3b8f8c24dd8237
출처 데이터셋: uspto-grants-1984_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04435425

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참가 물질

반응물 1

HCID 13273321HCID 13273321, 화합물

생성물 1

HCID 13273322HCID 13273322, 화합물

시약·촉매·용매 1

HCID 6422Trifluoroacetic acid용매

실험 절차

후처리

customthe solvent is evaporated in vacuo
customyielding a white solid

출처 및 근거

ORD 기록: ord-1e2125984a1e4bfcbf3b8f8c24dd8237
출처 데이터셋: uspto-grants-1984_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04435425

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불러오는 중…