Ammonium nitrate → Cobalt(2+) bis(7,7-dimethyloctanoate)

HRID 1903696노트

반응식

HRID 1903696 반응식
[Co:1].[C:2]([OH:13])(=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9].C([O-])=O.[Na+].[N+]([O-])([O-])=O.[NH4+]>O>[C:2]([O-:13])(=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:9])([CH3:10])[CH3:11].[Co+2:1].[C:2]([O-:13])(=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:9])([CH3:10])[CH3:11]

참가 물질

6

반응물 4

HCID 22985Ammonium nitrateHCID 62838Versatic 10HCID 104730CobaltHCID 2723810Sodium Formate

생성물 1

HCID 21972107Cobalt(2+) bis(7,7-dimethyloctanoate)

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
85 °C

실험 절차

A mixture of 50 grams of cobalt powder, 316.2 grams (1.697 moles) of neodecanoic acid (acid number, 301), a catalyst solution prepared by dissolving 5 grams of sodium formate and 5 grams of ammonium nitrate in 30 grams of water, and 130 grams of mineral spirits was heated at 85° C. for 7 hours while it was sparged with air at the rate of 30 liters per hour. The reaction mixture was heated at 135° C. under vacuum to remove water from it, filtered, and diluted with mineral spirits. There was obtained a solution of cobalt neodecanoate in mineral spirits that contained 10% cobalt and had an acid number of 18.

후처리

  1. customa catalyst solution prepared
  2. customwas sparged with air at the rate of 30 liters per hour
  3. temperatureThe reaction mixture was heated at 135° C. under vacuum
  4. customto remove water from it
  5. filtrationfiltered
  6. additiondiluted with mineral spirits

출처 및 근거

ORD 기록
ord-e38f138075104e7b9ecf053bf7bae127
출처 데이터셋
uspto-grants-1984_03
특허 번호
US04438038

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