Methanesulfonyl chloride → HCID 13208942, 화합물

HRID 1905967노트

반응식

[F:1][C:2]1[CH:7]=[CH:6][C:5]([CH2:8][CH2:9][O:10][CH2:11][CH2:12][OH:13])=[CH:4][CH:3]=1.[CH3:14][S:15](Cl)(=[O:17])=[O:16]>>[CH3:14][S:15]([O:13][CH2:12][CH2:11][O:10][CH2:9][CH2:8][C:5]1[CH:4]=[CH:3][C:2]([F:1])=[CH:7][CH:6]=1)(=[O:17])=[O:16]

참가 물질

반응물 2

HCID 31297Methanesulfonyl chloride

HCID 13208930HCID 13208930, 화합물

생성물 1

HCID 13208942HCID 13208942, 화합물수율 87%

실험 절차

The 2-[2-(4-fluorophenyl)ethoxy]ethanol obtained according to the preceding paragraph was sulfonylated with methanesulfonyl chloride in a manner analogous to that described in Example 1(c) to give 8.2 g (87%) of 2-[2-(4-fluorophenyl)ethoxy]ethyl methanesulfonate in the form of an oil which was homogeneous according to chromatography.

출처 및 근거

ORD 기록: ord-fbc0bf5fcac74b00923245a4402dc2e8
출처 데이터셋: uspto-grants-1987_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04649160

반응 노트

불러오는 중…