Dabco → Diethylaminoethyl 2-(1-hydroxycarbethoxymethyl)-acrylate

HRID 1906593

반응식

HRID 1906593 반응식
[C:1]([O:5][CH2:6][CH3:7])(=[O:4])[CH:2]=O.[C:8]([O:12][CH2:13][CH2:14][N:15]([CH2:18][CH3:19])[CH2:16][CH3:17])(=[O:11])[CH:9]=[CH2:10].C1N2CCN(CC2)C1.[O:28]1CCOCC1>>[OH:4][CH:1]([CH3:2])[O:5][C:6]([CH2:7][C:9](=[CH2:10])[C:8]([O:12][CH2:13][CH2:14][N:15]([CH2:18][CH3:19])[CH2:16][CH3:17])=[O:11])=[O:28]

참가 물질

5

반응물 4

HCID 9237DabcoHCID 170502-(Diethylamino)ethyl acrylateHCID 312751,4-DioxaneHCID 70211Ethyl oxoacetate

생성물 1

HCID 86741359Diethylaminoethyl 2-(1-hydroxycarbethoxymethyl)-acrylate수율 54%

실험 절차

51 g (0.5 mole) of ethyl glyoxylate, 85.5 g (0.5 mole) of N,N-diethylaminoethyl acrylate and 5 g (62.5 millimoles) of DABCO in 100 ml of absolute dioxane are reacted by a method similar to that described in Example 6. 74 g (54% of theory) of diethylaminoethyl 2-(1-hydroxycarbethoxymethyl)-acrylate are obtained.

출처 및 근거

ORD 기록
ord-72f6b8d625a8495f9d1d729303c6e6ec
출처 데이터셋
uspto-grants-1987_03
특허 번호
US04652669

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