Trimethylsilyldiazomethane → HCID 86657035, 화합물
반응식
[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]=[C:9]([C:11]([CH3:13])=[CH2:12])[N:10]=1)[C:5]([OH:7])=[O:6].[N+](=[CH:16][Si](C)(C)C)=[N-]>ClCCl.CO>[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]=[C:9]([C:11]([CH3:13])=[CH2:12])[N:10]=1)[C:5]([O:7][CH3:16])=[O:6]참가 물질
5
실험 절차
To a solution of 2-chloro-6-isopropenylisonicotinic acid (0.25 g, 1.27 mmol) in dichloromethane (4.7 mL) and methanol (1.6 mL) was added (diazomethyl)(trimethyl)silane (0.63 mL, 1.27 mmol). After the addition, the mixture was concentrated and carried onto the next step. MS 212.0 (M+1).
후처리
- additionAfter the addition
- concentrationthe mixture was concentrated
출처 및 근거
- ORD 기록
- ord-2d08f2d3334a4f7a87fc2643116b1aef
- 출처 데이터셋
- uspto-grants-2013_12
- 특허 번호
- US08598209B2
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