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Propionic Acid → HCID 86653825, 화합물

HRID 1913995
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HRID 1913995 반응식
[OH:1][CH:2]([CH:13]([OH:23])[CH2:14][CH:15]([OH:22])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([OH:12])=[O:11].C(O[C:29](=O)[CH2:30][CH3:31])(=O)CC.[CH3:33][C:34]1[CH:39]=CN=C(N)C=1C.[C:42](O)(=O)[CH2:43][CH3:44].[C:47]1(C)C(C)=CC=CC=1>>[CH3:47][O:11][C:10](=[O:12])[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]([O:1][CH2:31][CH2:30][CH3:29])[CH:13]([O:23][CH2:42][CH2:43][CH3:44])[CH2:14][CH:15]([O:22][CH2:33][CH2:34][CH3:39])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]
참가 물질반응 조건실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 5

HCID 1032Propionic AcidHCID 7237O-Xylene2회HCID 31263Propionic anhydride2회HCID 42527429,10,12-trihydroxyoctadecanoic AcidHCID 110078842-Amino-3,4-dimethylpyridine

생성물 1

HCID 86653825HCID 86653825, 화합물

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온도
180 °C

실험 절차

9,10,12-Trihydroxy octadecanoic acid rich fatty acid methyl esters (300 g) as prepared in example 1 was taken in one lit R.B.Flask and to this added propanoic anhydride (681 g), Dimethyl amino pyridine (DMAP, 300 mg) and xylene (100 ml) and stirred the contents magnetically at 180° C. for 6 hr. The course of the reaction was monitored by TLC. After completion of the reaction xylene and unconverted propanoic anhydride and propanoic acid were distilled under reduced pressure and the residue was taken in ethyl acetate. The ethyl acetate extract was washed with distilled water and passed through anhydrous sodium sulphate and concentrated under vacuum to recover the product (270 g) having an A.V. of 0.3, H.V. of 3.3 and I.V. of 2.0. The product was evaluated for viscosity, viscosity index (V.I.), pour point, flash point and copper strip corrosion and the data is provided in the following table.

후처리

  1. distillationwere distilled under reduced pressure
  2. extractionThe ethyl acetate extract
  3. washwas washed with distilled water
  4. concentrationconcentrated under vacuum
  5. customto recover the product (270 g)
  6. additionpour point, flash point and copper strip corrosion
  7. customthe data is provided in the following table

출처 및 근거

ORD 기록
ord-09263666a4034a9486b01a4e7d103301
출처 데이터셋
uspto-grants-2013_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08609876B2

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