Ammonia → Ammonium nitrate

HRID 1915980노트

반응식

[NH2:1][NH2:2].[N+:3]([O-:6])([O-:5])=[O:4].[NH4+].N>>[N+:3]([O-:6])([OH:5])=[O:4].[NH2:1][NH2:2].[N+:3]([O-:6])([O-:5])=[O:4].[NH4+:3]

참가 물질

반응물 3

HCID 222Ammonia2회

HCID 9321Hydrazine

HCID 22985Ammonium nitrate

생성물 2

HCID 22985Ammonium nitrate

HCID 166817Hydrazine, mononitrate

실험 절차

Hydrazine nitrate (HN) was prepared by reacting anhydrous hydrazine with an equivalent amount of ammonium nitrate. Formation took place by displacement of the ammonia as a gas. In production the ammonia would be scavenged by passing it through an aqueous nitric acid solution trap to form ammonium nitrate, which could then be used to prepare more HN. The HN product was purified by crystallization from methanol. This process was quite safe because it eliminated the need to neutralize the hydrazine with nitric acid. The procedure used is as follows.

출처 및 근거

ORD 기록: ord-0d64f0441d1f4304b9ffb109bf28693e
출처 데이터셋: uspto-grants-2013_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08617327B1

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