Chlorosulfonic acid → HCID 59180414, 화합물

HRID 1925731노트

반응식

HRID 1925731 반응식
[C:1]([C:5]1[CH:10]=[CH:9][CH:8]=[C:7]([I:11])[CH:6]=1)([CH3:4])([CH3:3])[CH3:2].Cl[S:13]([OH:16])(=[O:15])=[O:14]>ClCCl>[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:13]([OH:16])(=[O:15])=[O:14])=[C:7]([I:11])[CH:6]=1)([CH3:4])([CH3:2])[CH3:3]

참가 물질

4

반응물 2

HCID 24638Chlorosulfonic acidHCID 6379581-tert-butyl-3-iodobenzene

생성물 1

HCID 59180414HCID 59180414, 화합물수율 95.1%

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

Synthesized as described for 1 using 1-tert-butyl-3-iodobenzene (9.65 g; 37.09 mmol), chlorosulfonic acid (3.20 mL; 48.22 mmol), and anhydrous dichloromethane (140 mL). Trituration of the crude product from hexanes yielded the title compound as a brown oil (12.0 g).

후처리

  1. customSynthesized

출처 및 근거

ORD 기록
ord-1e75d69e8fc84c3f8644320ddb5927e4
출처 데이터셋
uspto-grants-2012_05
특허 번호
US08178699B2

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