3-Phenyl-3,4-dihydro-1(2h)-naphthalenone → 1-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole

HRID 1935758노트

반응식

HRID 1935758 반응식
[CH2:1]([N:8]1[C:12]([CH:13]=C2C3C(=CC=CC=3)CC2C2C=CC=CC=2)=[CH:11][N:10]=[CH:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:29]1([CH:35]2[CH2:44][C:43]3[C:38](=[CH:39][CH:40]=[CH:41][CH:42]=3)[C:37](=O)[CH2:36]2)[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1>>[CH2:1]([N:8]1[C:12]([CH:13]=[C:37]2[C:38]3[C:43](=[CH:42][CH:41]=[CH:40][CH:39]=3)[CH2:44][CH:35]([C:29]3[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=3)[CH2:36]2)=[CH:11][N:10]=[CH:9]1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

참가 물질

3

반응물 2

HCID 5765563-Phenyl-3,4-dihydro-1(2h)-naphthalenoneHCID 698316891-Benzyl-5-(2-phenylindan-1-ylidenemethyl)-1H-imidazole

생성물 1

HCID 698323401-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole

실험 절차

1-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole was prepared as 1-benzyl-5-(2-phenylindan-1-ylidenemethyl)-1H-imidazole above except that 3-phenyl-3,4-dihydro-2H-naphthalen-1-one (prepared according to J. Vebrel and R. Carrie Bull. Soc. Chem. Fr. (1982) 116) was used as a starting material. The crude product as its hydrochloride salt was used in the next step without purification.

후처리

  1. customThe crude product as its hydrochloride salt was used in the next step without purification

출처 및 근거

ORD 기록
ord-0e94f973d3c04c48978de6e9913b0df9
출처 데이터셋
uspto-grants-2002_05
특허 번호
US06388090B2

반응 노트

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