Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,2-Dichloroethane → 1,1,1,4,4,4-Hexachloro-1,4-disilabutane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,2-Dichloroethane | HCID 11 | — |
| 반응물 | Trichlorosilane | HCID 24811 | — |
| 촉매 | Tetrabutylphosphonium chloride | HCID 75311 | — |
| 생성물 | 1,1,1,4,4,4-Hexachloro-1,4-disilabutane | HCID 75631 | 54% |
반응 단계
In the same apparatus and procedure as Example 1 above, 0.44 g (1.50 mmol) of tetrabutylphosphonium chloride, 0.74 g (7.5 mmol) of 1,2-dichloroethane, and 10.16 g (75.0 mmol) of trichlorosilane were reacted at 150° C. for 10 hrs. The resulting mixture was distilled to give 1.09 g of 1,2-bis(trichlorosilyl)ethane (yield; 54%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06392077B1 |
| 출처 데이터셋 | uspto-grants-2002_05 |
| ORD ID | ord-3a676ac9546048e5bab7a6b305272eae |
| 출처 메모 | uspto-grants-2002_05 |