Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,3-Dichloropropane → 1,3-Bis(trichlorosilyl)propane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,3-Dichloropropane | HCID 8881 | — |
| 반응물 | Trichlorosilane | HCID 24811 | — |
| 촉매 | Tetrabutylphosphonium chloride | HCID 75311 | — |
| 생성물 | Trichloro(3-chloropropyl)silane | HCID 75693 | 14% |
| 생성물 | 1,3-Bis(trichlorosilyl)propane | HCID 11243856 | 72% |
반응 단계
In the same apparatus and procedure as Example 1 above, 0.44 g (1.50 mmol) of tetrabutylphosphonium chloride, 0.85 g (7.5 mmol) of 1,3-dichloropropane, and 10.16 g (75.0 mmol) of trichlorosilane were reacted at 150° C. for 10 hrs. The resulting mixture was distilled to give 1.68 g of 1,3-bis(trichlorosilyl)propane (yield; 72%) and 0.22 g of (3-chloropropyl)trichlorosilane (yield; 14%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06392077B1 |
| 출처 데이터셋 | uspto-grants-2002_05 |
| ORD ID | ord-4e600918000f4c37a1bb05bb1f3d518f |
| 출처 메모 | uspto-grants-2002_05 |