참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 2-Heptanol | HCID 10976 | — |
| 반응물 | Ethyl 2-(pyridin-2-yloxy)acetate | HCID 21464941 | — |
| 촉매 | Titanium isopropoxide | HCID 11026 | — |
| 생성물 | (1-Methyl)hexyl 2-pyridyloxyacetate | HCID 21464939 | 90% |
반응 단계
5.0 g (28 mmol) of ethyl 2-pyridyloxyacetate were suspended in 100 ml of 2-heptanol, 1 ml of titanium tetraisopropoxide were added, and the mixture was stirred for 4 hours at 120° C. The excess 2-heptanol was subsequently distilled off under an oil pump vacuum, and the residue was purified by column chromatography. 6.2 g (90% of theory) of (1-methyl)hexyl 2-pyridyloxyacetate were obtained as a colorless oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05698539 |
|---|
| 출처 데이터셋 | uspto-grants-1997_12 |
|---|
| ORD ID | ord-240782b943054781b8e440bec68b2785 |
|---|
| 출처 메모 | uspto-grants-1997_12 |
|---|
