Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(1,1'-Biphenyl)-4-carboxylic acid → (1,1'-Bi(cyclohexane))-4-carboxylic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (1,1'-Biphenyl)-4-carboxylic acid | HCID 66724 | — |
| 촉매 | Rhodium | HCID 23948 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Ethyl Acetate | HCID 8857 | — |
| 생성물 | (1,1'-Bi(cyclohexane))-4-carboxylic acid | HCID 3062287 | 93.5% |
반응 단계
Reduce a solution of 4-biphenylcarboxylic acid (10 g) in ethanol (EtOH) (175 mL) and EtOAc (30 mL) over 5% rhodium/alumina (7 g) under H2 (60 psi) for 8 days. Filter the catalyst and concentrate the solution to obtain the title compound (9.92 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05698548 |
| 출처 데이터셋 | uspto-grants-1997_12 |
| ORD ID | ord-99b5569094014fa7afb6336024ea3b65 |
| 출처 메모 | uspto-grants-1997_12 |