(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal → L-Rhamnitol

HRID 1941743노트

반응식

HRID 1941743 반응식
[O:1]=[CH:2][C@@H:3]([C@@H:5]([C@H:7]([C@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])[OH:4].[CH2:12]([OH:22])[C@@H:13]([C@@H:15]([C@H:17]([C@H:19]([CH3:21])[OH:20])[OH:18])[OH:16])[OH:14]>>[CH2:2]([OH:1])[C@@H:3]([C@@H:5]([C@H:7]([C@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])[OH:4].[OH:22][CH2:12][C:13]([C@@H:15]([C@H:17]([C@H:19]([CH3:21])[OH:20])[OH:18])[OH:16])=[O:14].[CH3:11][C:9]([C@@H:7]([C@H:5]([C@H:3]([CH2:2][OH:1])[OH:4])[OH:6])[OH:8])=[O:10]

참가 물질

5

반응물 2

HCID 19233(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanalHCID 445052L-Rhamnitol2회

생성물 3

HCID 445052L-RhamnitolHCID 14461866HCID 14461866, 화합물HCID 22820975(3R,4S,5S)-3,4,5,6-tetrahydroxyhexan-2-one

실험 절차

6-Deoxy L-mannitol can readily be produced via chemical reduction of 6-deoxy L-mannose. At a productivity close to 99%, 6-deoxy L-mannose is completely converted to 6-deoxy L-mannitol. When the initial concentrations of 6-deoxy L-mannitol were 3%, 4% and 5%, almost 90%, 70% and 65%, respectively of 6-deoxy L-mannitol produced 6-deoxy L-fructose and 1-deoxy L-fructose, using the washed bacterial cell reaction.

출처 및 근거

ORD 기록
ord-9f418bbc4fbe49e19dc7f904031fa364
출처 데이터셋
uspto-grants-2013_03
특허 번호
US08389248B2

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