Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → N-(10,11-Dihydroxyundecyl)phthalimide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Sodium Sulfite | HCID 24437 | — |
| 반응물 | Methyl morpholine oxide | HCID 82029 | — |
| 반응물 | 2-(Undec-10-en-1-yl)-1H-isoindole-1,3(2H)-dione | HCID 22044522 | — |
| 용매 | Propan-2-one--water (1/1) | HCID 18366337 | — |
| 생성물 | N-(10,11-Dihydroxyundecyl)phthalimide | HCID 12988906 | 71% |
반응 단계
A solution of N-(10-Undecenyl)phthalimide (4.97 g, 16.6 mmol), prepared as discribed above, 4-methylmorpholine-N-oxide (8.62 mL, 60% by wt in water, 50.0 mmol) and potassium osmate dihydrate (58 mg, 0.16 mmol) in 100 mL acetone/water (1:1 by wt) was stirred for 16 hours. Water (100 mL) and sodium sulfite (10 g) were added and the resulting solution stirred for an additional hour. The resulting reaction mixture was extracted with dichloromethane (3×80 mL) and the organic phase dried using magnesium sulfate and evaporated to obtain 3.93 g (71% yield) of N-(10,11-Dihydroxyundecyl)phthalimide (inventive compound no. 1108).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06121270 |
| 출처 데이터셋 | uspto-grants-2000_09 |
| ORD ID | ord-9af6a0e9aced468eb14b94b8094ab703 |
| 출처 메모 | uspto-grants-2000_09 |