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Dimethylidenebutanedinitrile → HCID 86734279, 화합물

HRID 1973703
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반응식

HRID 1973703 반응식
[CH2:1]=[C:2]([C:7]#[N:8])[C:3]([C:5]#[N:6])=[CH2:4].C(C#N)CC=[CH:12][CH2:13][CH:14]([C:18]#[N:19])[CH2:15][CH2:16][CH3:17]>C(Cl)Cl>[CH2:3]([C:5]#[N:6])[CH2:2][CH2:1][CH2:1][C:2]([C:7]#[N:8])=[C:3]([C:5]#[N:6])[CH2:4][CH2:12][CH2:13][CH:14]([C:18]#[N:19])[CH2:15][CH2:16][CH3:17]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

4

반응물 2

HCID 12362041DimethylidenebutanedinitrileHCID 86734280HCID 86734280, 화합물2회

생성물 1

HCID 86734279HCID 86734279, 화합물

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

A further preparation employed 1,3-butadiene-2,3-dicarbonitrile in a condensation reaction with 9-oxatricyclo[4.2.12,5.0]non-3-ene-1,6-dicarbonitrile utilizing methylene chloride as diluent under room temperature conditions and a contacting time of about 5 days. By this method, a conversion of about 50 percent was obtained based on the 9-oxatricyclo[4.2.12,5.0]non-3-ene-1,6-dicarbonitrile, resulting in nearly 100 percent ultimate yields of 13-oxatetracyclo[8.2.12,9.0.03,8 ]tridec-5-ene-1,5,6,10-tetracarbonitrile.

후처리

  1. customA further preparation
  2. customdiluent under room temperature
  3. customa contacting time of about 5 days
  4. customBy this method, a conversion of about 50 percent was obtained
  5. customresulting in nearly 100 percent

출처 및 근거

ORD 기록
ord-de27b2127843425cba5be0eb2657c038
출처 데이터셋
uspto-grants-1976_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US03998853

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