2,4-Dinitrobenzenesulfenyl chloride → Sulfide, bis(2,4-dinitrophenyl)

HRID 1973772

반응식

HRID 1973772 반응식
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13]Cl)([O-:3])=[O:2]>C(O)(=O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])([O-:3])=[O:2]

참가 물질

3

반응물 1

HCID 682512,4-Dinitrobenzenesulfenyl chloride

생성물 1

HCID 95960Sulfide, bis(2,4-dinitrophenyl)

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

To 1.38 g. of 3-butenyltributyltin was added 0.936 g. of 2,4-dinitrobenzene sulfenyl chloride in 20 ml. glacial acetic acid at steam bath temperature. The reaction mixture was warmed on the steam bath for 20 minutes, poured into ice water and filtered. The mixture was extracted with pentane, dried and recrystallized from ethanol to yield cyclopropylcarbinyl 2,4-dinitrophenyl sulfide; m.p. 80° -81° C. Analysis for C and H confirmed the composition of the reaction product.

후처리

  1. temperatureThe reaction mixture was warmed on the steam bath for 20 minutes
  2. filtrationfiltered
  3. extractionThe mixture was extracted with pentane
  4. customdried
  5. customrecrystallized from ethanol

출처 및 근거

ORD 기록
ord-ed8d129d868f415b83b0ed6db7603d49
출처 데이터셋
uspto-grants-1976_12
특허 번호
US03998889

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