Allylamine → HCID 21490733, 화합물

반응식

[C:1]([OH:13])(=O)[CH2:2][CH:3]1[CH:11]=[CH:10][CH2:9][CH2:8][CH:4]1[C:5]([OH:7])=O.[CH2:14]([NH2:17])[CH:15]=[CH2:16]>>[CH2:14]([N:17]1[C:1](=[O:13])[CH2:2][C:3]2[CH2:11][CH2:10][CH2:9][CH2:8][C:4]=2[C:5]1=[O:7])[CH:15]=[CH2:16]

참가 물질

반응물 2

HCID 7853Allylamine

HCID 131710580HCID 131710580, 화합물

생성물 1

HCID 21490733HCID 21490733, 화합물

실험 절차

A mixture of tetrahydrohomophthalic acid (9.2 g., 0.05 mole) and allylamine (2.8 g., 0.05 mole) is heated by an oil bath until molten for 40 minutes. The mixture solidifies upon cooling, and is recrystallized twice from isopropanol, giving 2-allyl-5,6,7,8-tetrahydroisoquinoline-1,3(2H, 4H)-dione.

후처리

temperatureis heated by an oil bath until molten for 40 minutes
temperatureupon cooling
customis recrystallized twice from isopropanol

출처 및 근거

ORD 기록: ord-dc18d779806e4351ac8fc00a11e9100e
출처 데이터셋: uspto-grants-1976_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03998954

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