(1S,4aS,6S,7R,7aR)-6,7-epoxy-1,4a,5,6,7,7a-hexahydro-1-(methylcarbamoyloxy)cyclopenta[c]-pyrane-4-carboxylic acid dimethylamide → (1S,4aS,6S,7R,7aR)-6,7-epoxy-1,4a,5,6,7,7a-hexahydro-7-methyl-1-(methylcarbamoyloxy) cyclopenta [c]-pyrane-4-carboxylic acid

반응식

C[N:2]([CH3:20])[C:3]([C:5]1[C@H:6]2C[C@@H]3O[C@@H]3[C@@H:7]2[C@H:8](OC(=O)NC)OC=1)=[O:4].[CH2:21]([N:23](CC)[C:24]([C:26]1[C@H:27]2[CH2:39][C@@H:38]3[O:40][C@:37]3([CH3:41])[C@@H:28]2[C@H:29]([O:32][C:33](=[O:36])[NH:34][CH3:35])[O:30][CH:31]=1)=[O:25])[CH3:22]>>[N:2]1([NH:23][C:24]([C:26]2[C@H:27]3[CH2:39][C@@H:38]4[O:40][C@:37]4([CH3:41])[C@@H:28]3[C@H:29]([O:32][C:33](=[O:36])[NH:34][CH3:35])[O:30][CH:31]=2)=[O:25])[CH2:3][CH2:5][CH2:6][CH2:20]1.[CH2:21]([NH:23][C:24]([C:26]1[C@H:27]2[CH2:39][C@@H:38]3[O:40][C@:37]3([CH3:41])[C@@H:28]2[C@H:29]([O:32][C:33](=[O:36])[NH:34][CH3:35])[O:30][CH:31]=1)=[O:25])[C:22]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:3]=1.[O:40]1[C@@:37]2([CH3:41])[C@@H:38]1[CH2:39][C@@H:27]1[C:26]([C:24]([OH:25])=[O:4])=[CH:31][O:30][C@@H:29]([O:32][C:33](=[O:36])[NH:34][CH3:35])[C@H:28]12