glucosamine tetra-O-acetate → 2-nitro-4-[3',5'-bis(ethyl)-2',4',6'-triiodophenyl]-benzoyl-1,3,4,6-tetra-O-acetyl-D-glucosamine

HRID 1976513

반응식

HRID 1976513 반응식
[C:1]([O:4][CH:5]1[O:19][C@H:18]([CH2:20][O:21][C:22](=[O:24])[CH3:23])[C@@H:13]([O:14][C:15](=[O:17])[CH3:16])[C@H:8]([O:9][C:10](=[O:12])[CH3:11])[C@H:6]1[NH2:7])(=[O:3])[CH3:2].[I:25][C:26]1[C:31]([CH2:32][CH3:33])=[C:30]([I:34])[C:29]([CH2:35][CH3:36])=[C:28]([I:37])[C:27]=1[C:38]1[CH:43]=[CH:42][C:41]([C:44](Cl)=[O:45])=[C:40]([N+:47]([O-:49])=[O:48])[CH:39]=1>>[N+:47]([C:40]1[CH:39]=[C:38]([C:27]2[C:28]([I:37])=[C:29]([CH2:35][CH3:36])[C:30]([I:34])=[C:31]([CH2:32][CH3:33])[C:26]=2[I:25])[CH:43]=[CH:42][C:41]=1[C:44]([C:5]1([O:19][C@H:18]([CH2:20][O:21][C:22](=[O:24])[CH3:23])[C@@H:13]([O:14][C:15](=[O:17])[CH3:16])[C@H:8]([O:9][C:10](=[O:12])[CH3:11])[C@H:6]1[NH2:7])[O:4][C:1](=[O:3])[CH3:2])=[O:45])([O-:49])=[O:48]

참가 물질

3

반응물 2

HCID 13059363glucosamine tetra-O-acetateHCID 223420022',4',6'-Triiodo-3',5'-bis(ethyl)-3-nitrobiphenyl-4-carbonyl chloride

생성물 1

HCID 865835222-nitro-4-[3',5'-bis(ethyl)-2',4',6'-triiodophenyl]-benzoyl-1,3,4,6-tetra-O-acetyl-D-glucosamine

실험 절차

1,3,4,6-tetra-O-acetyl-D-glucosamine (9) is reacted with 2′,4′,6′-triiodo-3′,5′-bis(ethyl-3-nitrobiphenyl-4-carbonyl chloride (19) to yield 2-nitro-4-[3′,5′-bis(ethyl)-2′,4′,6′-triiodophenyl]benzoyl-1,3,4,6-tetra-O-acetyl-D-glucosamine (20).

출처 및 근거

ORD 기록
ord-5cd3c3d8210940eeb6cfa6a1937f37d8
출처 데이터셋
uspto-grants-2001_05
특허 번호
US06226352B1

연결된 노트

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