Acetic Acid → Maleic Acid

반응식

[N+]([O-])([O-])=O.[K+].[C:6]([OH:11])(=[O:10])[C:7]([CH3:9])=[CH2:8].[C:12]([OH:15])(=[O:14])C>>[C:12]([OH:15])(=[O:14])/[CH:8]=[CH:7]\[C:6]([OH:11])=[O:10].[C:6]([OH:11])(=[O:10])/[C:7](=[CH:9]\[C:12]([OH:15])=[O:14])/[CH3:8]

참가 물질

반응물 3

HCID 176Acetic Acid

HCID 4093Methacrylic Acid

HCID 24434Potassium Nitrate

생성물 2

HCID 444266Maleic Acid

HCID 643798Citraconic acid

실험 절차

A catalyst is prepared as described in Example 1 except that the addition of potassium nitrate is omitted. Under the test conditions of Example 1 and at a bath temperature of 310° C., the conversion is 69.9 mole %, and the selectivities with respect to methacrylic acid and acetic acid are 82.5 mole % and 3.7 mole % respectively. Maleic acid and citraconic acid are formed in a total amount of 1.2%.