Sodium methanethiolate → HCID 18434372, 화합물
반응식
[Br:1][C:2]1[CH:7]=[CH:6][C:5](CBr)=[C:4]([N+:10]([O-:12])=[O:11])[CH:3]=1.[CH3:13][S-:14].[Na+]>O1CCCC1>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:14][CH3:13])=[C:4]([N+:10]([O-:12])=[O:11])[CH:3]=1참가 물질
4
실험 절차
A suspension of 4-bromo-1-(bromomethyl)-2-nitrobenzene (1.0 g) and sodium methanethiolate (0.285 g) in tetrahydrofuran (20 ml) was stirred under nitrogen for 60 h. The solvent was evaporated, chloroform (50 ml) was added and the rsidual solid was removed by filtration. The filtrate was comncentrated under vacuum to give the title compound (0.89 g).
후처리
- customThe solvent was evaporated
- additionchloroform (50 ml) was added
- customthe rsidual solid was removed by filtration
출처 및 근거
- ORD 기록
- ord-9f04f6de723e4ac1822b9b8dab7cc130
- 출처 데이터셋
- uspto-grants-2010_01
- 특허 번호
- US07642276B2
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