HCID 88662971, 화합물 → HCID 70436618, 화합물

HRID 1995047노트

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HRID 1995047 반응식
[S:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[CH2:6][C:7]([NH:9][CH:10]1[C:25](=[O:26])[N:12]2[C:13]([C:22]([OH:24])=[O:23])=[C:14](OS(C)(=O)=O)[CH2:15][S:16][C@H:11]12)=[O:8]>C(O)C>[S:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[CH2:6][C:7]([NH:9][CH:10]1[C:25](=[O:26])[N:12]2[C:13]([C:22]([OH:24])=[O:23])=[CH:14][CH2:15][S:16][C@H:11]12)=[O:8]

참가 물질

3

반응물 1

HCID 88662971HCID 88662971, 화합물

생성물 1

HCID 70436618HCID 70436618, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

A 200 mg. portion of 7-(thien-2-ylacetamido)-3-methanesulfonyloxyl-3-cephem-4-carboxylic acid was dissolved in a working fluid containing 2.5 mg./ml. of the starting compound, 35% by volume of ethanol, and 64% by volume of 1.0 molar pH 7.0 McIlvaine buffer. The measured pH of the working fluid was 7.5. The electrolysis was carried out as described in Example 1 in the same type of cell described in Example 1, and the product was worked up as described in Example 2 to obtain about 130 mg. of crude product. The product was converted to the methyl ester, and submitted to mass spectroscopy, which revealed the presence of molecular ions of mass 337 and 338, confirming that the desired product was obtained.

후처리

  1. additioncontaining 2.5 mg
  2. customto obtain about 130 mg

출처 및 근거

ORD 기록
ord-2752ce02705b4e3eb6d41414307422b3
출처 데이터셋
uspto-grants-1983_09
특허 번호
US04402803

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