Methanol → Methyl 3-oxocyclopent-1-enecarboxylate

HRID 2001551

반응식

HRID 2001551 반응식
[O:1]=CN1S(=O)(=O)[c:8]([c:4]2[C:2]1=[O:3])[cH:7]c[cH:6][cH:5]2.[CH3:9][OH:10].Cc1ccc(S(OC(CCC2=O)=C2)(=O)=O)cc1>>[CH3:9][O:10][C:2]([C:4]([CH2:8][CH2:7][C:6]1=[O:1])=[CH:5]1)=[O:3]

참가 물질

8

반응물 3

HCID 887MethanolHCID 546716891,1,3-Trioxo-1,3-dihydro-2H-1lambda~6~,2-benzothiazole-2-carbaldehydeHCID 86196686(3-Oxocyclopenten-1-yl) 4-methylbenzenesulfonate

생성물 1

HCID 11029917Methyl 3-oxocyclopent-1-enecarboxylate

시약·촉매·용매 4

HCID 516892Sodium Bicarbonate시약HCID 2734558Bis(tri-tert-butylphosphine)palladium(0)촉매HCID 887Methanol용매HCID 117669-Phenylanthracene내부 표준

반응 조건

온도
110 °C

출처 및 근거

ORD 기록
ord-20dd770c09d2416cbc41a8ac6a12005f
출처 데이터셋
39k HTE dataset from Pfizer
원본 링크
출처 보기

연결된 노트

불러오는 중…