5-(4-Chlorophenyl)-2-[(dimethylamino)methylene]-1,3-cyclohexanedione → 2-Dimethylaminomethylene-5-phenyl-cyclohexane-1,3-dione

반응식

C1(C2CC(=O)CC(=O)C2)C=CC=CC=1.Cl[C:16]1[CH:21]=[CH:20][C:19]([CH:22]2[CH2:27][C:26](=[O:28])[C:25](=[CH:29][N:30]([CH3:32])[CH3:31])[C:24](=[O:33])[CH2:23]2)=[CH:18][CH:17]=1>>[CH3:32][N:30]([CH:29]=[C:25]1[C:26](=[O:28])[CH2:27][CH:22]([C:19]2[CH:20]=[CH:21][CH:16]=[CH:17][CH:18]=2)[CH2:23][C:24]1=[O:33])[CH3:31]

참가 물질

반응물 2

HCID 5670705-(4-Chlorophenyl)-2-[(dimethylamino)methylene]-1,3-cyclohexanedione

HCID 5689621,3-Cyclohexanedione, 5-phenyl-

생성물 1

HCID 108901102-Dimethylaminomethylene-5-phenyl-cyclohexane-1,3-dione

실험 절차

The title compound was prepared from 5-phenylcyclohexane-1,3-dione (1.0 g, 5.3 mmol), following the procedure described for the synthesis of 5-(4-chloro-phenyl)-2-dimethylaminomethylene-cyclohexane-1,3-dione (example 2/a stage 1) except that the reaction was run at ambient temperature for 30 min.

출처 및 근거

ORD 기록: ord-0128f0eba9e84a23a2e582bf1bd4a1de
출처 데이터셋: uspto-grants-2013_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08592430B2

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