Thiocyanic acid, chloromethyl ester → 3-Trifluoromethyl-thiobenzoic acid thiocyanomethyl ester
반응식
[F:1][C:2]([F:13])([F:12])[C:3]1[CH:4]=[C:5]([CH:9]=[CH:10][CH:11]=1)[C:6]([OH:8])=[S:7].Cl[CH2:15][S:16][C:17]#[N:18]>>[S:16]([CH2:15][O:8][C:6](=[S:7])[C:5]1[CH:9]=[CH:10][CH:11]=[C:3]([C:2]([F:1])([F:12])[F:13])[CH:4]=1)[C:17]#[N:18]참가 물질
3
실험 절차
23 g (0.1 mol) of the K salt of 3-trifluoromethyl thiobenzoic acid and 14.3 g (0.13 mol) of chloromethyl thiocyanate were reacted and processed as in Example 1 B. 19 g of a yellowish oil having a density of 1.4 (this corresponds to a yield of 69% of the theoretical conversion).
출처 및 근거
- ORD 기록
- ord-aa3a7781ad23430db1f2ed350d4ff60c
- 출처 데이터셋
- uspto-grants-1980_04
- 특허 번호
- US04198428
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