Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(Bromodichloromethyl)phenylmercury → HCID 20344549, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (Bromodichloromethyl)phenylmercury | HCID 76800 | — |
| 반응물 | Methyl 3-(4-chlorophenoxy)prop-2-enoate | HCID 53663470 | — |
| 용매 | Benzene | HCID 241 | — |
| 생성물 | HCID 20344549 | HCID 20344549 | — |
반응 단계
A mixture of methyl 3-(4-chlorophenoxy)-2-propenoate (30 mmol), phenyl(bromodichloromethyl)mercury (30 mmol) and 50 ml benzene are heated under reflux, with stirring, for 4 hr, followed by TLC of the product. The mixture is then filtered and the solvent removed, giving methyl 3-(4-chlorophenoxy)-2,2-dichlorocyclopropanecarboxylate, which is then hydrolyzed and reacted with m-phenoxybenzyl bromide to give m-phenoxybenzyl 3-(4-chlorophenoxy)-2,2-dichlorocyclopropanecarboxylate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04198527 |
| 출처 데이터셋 | uspto-grants-1980_04 |
| ORD ID | ord-08344fd5ddcf45489bc6732e73bd2fc0 |
| 출처 메모 | uspto-grants-1980_04 |