Sulfuric Acid → 5-Nitrofurfuryl alcohol

HRID 2050170

반응식

HRID 2050170 반응식
C([O:4][CH:5](OC(=O)C)[C:6]1[O:7][C:8]([N+:11]([O-:13])=[O:12])=[CH:9][CH:10]=1)(=O)C.OS(O)(=O)=O>O>[N+:11]([C:8]1[O:7][C:6]([CH2:5][OH:4])=[CH:10][CH:9]=1)([O-:13])=[O:12]

참가 물질

4

반응물 2

HCID 1118Sulfuric AcidHCID 70975-Nitro-2-furanmethanediol diacetate

생성물 1

HCID 172305-Nitrofurfuryl alcohol

시약·촉매·용매 1

HCID 962Water용매

실험 절차

2-(Diacetoxymethyl)-5-nitro-furane (48.6 pts. by wt.) are boiled in a mixture of water (216 pts. by vol.) and concentrated H2SO4 (108 pts. by wt.) for 15 minutes under N2, the mixture is then cooled and the 5-nitro-furfurol formed is taken up in ether and, after removing the ether, dissolved in 100 pts. by vol. of methanol. A solution of 1-amino-2-oxo-imidazolidine hydrochloride (27.5 pts. by wt.) in water (100 pts. by vol.) is added to this solution. After 4.5 hrs., the product which has separated out is filtered off, washed with water and dried.

후처리

  1. temperaturethe mixture is then cooled

출처 및 근거

ORD 기록
ord-8eb9a4b4b2a84e73b5379804703cfbd4
출처 데이터셋
uspto-grants-1980_04
특허 번호
US04200576

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