Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
17beta-(Hydroxymethyl)androst-4-ene-3-ol → 17beta-Hydroxymethyl-4-androsten-3-on
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 17beta-(Hydroxymethyl)androst-4-ene-3-ol | HCID 14801334 | — |
| 촉매 | HCID 178418406 | HCID 178418406 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | 17beta-Hydroxymethyl-4-androsten-3-on | HCID 14377617 | 96.6% |
반응 단계
A solution of 17β-(hydroxymethyl) -androst-4-ene 3 ol (27 g, 0.089 mol) in 1200 ml trichloromethane was treated with activated manganese dioxide (66 g). After 3 hours the mixture was filtered. Concentration afforded 26 g (96%) of 3-oxo-17β-(hydroxymethyl)-4 androstene (m.p. 151° C.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05017568 |
| 출처 데이터셋 | uspto-grants-1991_05 |
| ORD ID | ord-658304117daf44e3b80ae272c5c9ec75 |
| 출처 메모 | uspto-grants-1991_05 |