Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methyl iodide → N-(4-anilinophenyl)-N-(1,3-dimethyl-butyl)-dithiocarbamate methyl ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methyl iodide | HCID 6328 | — |
| 반응물 | Carbon Disulfide | HCID 6348 | — |
| 반응물 | 1,4-Benzenediamine, N-(1,3-dimethylbutyl)-N'-phenyl- | HCID 13101 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | N-(4-anilinophenyl)-N-(1,3-dimethyl-butyl)-dithiocarbamate methyl ester | HCID 19832493 | — |
반응 단계
N-phenyl-N'-(1,3-dimethylbutyl)-p-phenylenediamine (26.8g, 0.10 mol) is dissolved in 100 mL tetrahydrofuran in a 250 mL, 3-neck round bottom flask. Carbon disulfide (7.6g, 0.10 mol) is added over 0.5 hours with the concurrent addition of an aqueous solution of sodium hydroxide (4.0g, 0.10 mol). When addition is complete, methyl iodide (14.2g, 0.10 mol) is added and the mixture refluxed for 1 hour. The solvent is then stripped off on a rotary evaporator and the residue extracted with methylene chloride. The extract is dried with MgSO4 and the solvent is again removed on the rotary evaporator to yield the product.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05019611 |
| 출처 데이터셋 | uspto-grants-1991_05 |
| ORD ID | ord-bd7ddee354044392b7d9546781f462db |
| 출처 메모 | uspto-grants-1991_05 |