1,7-Octadien-3-ol → 1,7-Octadien-3-one

HRID 2051636노트

반응식

HRID 2051636 반응식
[CH2:1]=[CH:2][CH:3]([OH:9])[CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8]>[O-2].[O-2].[Mn+4].C(Cl)(Cl)(Cl)Cl>[CH2:1]=[CH:2][C:3](=[O:9])[CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8]

참가 물질

4

반응물 1

HCID 5457381,7-Octadien-3-ol

생성물 1

HCID 118047521,7-Octadien-3-one

시약·촉매·용매 2

HCID 178418406HCID 178418406, 화합물촉매HCID 5943Carbon Tetrachloride용매

실험 절차

To 100 cc of carbon tetrachloride containing 3.1 g of 1,7-octadien-3-ol (III) was added 10 g of active manganese dioxide, and the mixture was stirred at room temperature for 4 days. After filtration, the solvent (filtrate) was distilled off at a reduced pressure of 20 to 30 mm Hg to obtain 2 g of 1,7-octadien-3-one at 30°-32° C./4 mm Hg.

후처리

  1. filtrationAfter filtration
  2. distillationthe solvent (filtrate) was distilled off at a reduced pressure of 20 to 30 mm Hg

출처 및 근거

ORD 기록
ord-cb578c10fa4a46c7af9aa245df9633c2
출처 데이터셋
uspto-grants-1980_01
특허 번호
US04181683

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